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A Progression Relation in the Molecular Spectrum of Oxygen by Wulf O.R.

By Wulf O.R.

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This can be appreciated by considering that the absorption cross section depends on both the initial state and the final state of the absorber. The final state includes both the core hole and the photoelectron wave (2), and will therefore depend on the interference of the outgoing and backscattered waves. Constructive interference will give rise to a local maximum in absorption, while destructive interference results in a local minimum. As shown in Figure 2, the interference alternates between constructive and destructive as the X-ray energy is increased (thereby decreasing the photoelectron wavelength).

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