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a review of the literature abstracted between July 1980 and by H Suschitzky; O Meth-Cohn; Great Britain. The Royal Society

By H Suschitzky; O Meth-Cohn; Great Britain. The Royal Society of Chemistry

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Additional info for a review of the literature abstracted between July 1980 and June 1981

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Org. , 1980,45,2498. G . Snatzke, H. Wynberg, B. Feringa, B. G. Marsman, B. Greydanus, and H. Pluim, J. Org. , 1980,454094. K. Tani, M. Hanafusa, and S. , 1979, 3017. Terashima, M. Hayashi, and K. , 1980,21,2733. Boger and S. J. Panek, J. Org. , 1981,46,1208. S. Julia, J. Masana, and J. C. Vega, Angew. , Int. Ed. , 1980,929. 13 Three-Membered Ring Systems involves a three-phase system of toluene, water, and the synthetic enzyme poly-(S)-alanine, and it has great promise in that, for the first time, a readily accessible polypeptide has been used to provide epoxide in high optical yield with relatively short reaction time and with only a small amount of the enzyme catalyst needed.

Benz[a]anthracene is the member with the lowest molecular weight of the series of polycyclic aromatic hydrocarbons (PAH) to be generally considered a 7s 76 77 78 R. N. Armstrong, W. Levin, and D. M. Jerina, J. Biol. , 1980,255,4698. C. Cortez and R. G. Harvey, Org. , 1978,58,12. W. H. Rastetter and L. J. Nummy, J. Org. , 1980,45,3149. J. McCaustland, P. H. Ruehle, and J. C. , J. Chem. ,Chem. , 1980,93. 14 Heterocyclic Chemistry carcinogen. The 8,9-oxide (86), a major initial metabolite of this compound, The major isolated has been synthesized in optically pure (+)- and liver metabolite of (86) is a diol with 8R,9R stereochemistry, and this has been shown to be enzymatically derived from the (+)-isomer.

Tanaka, Bull. Chem. Soc. , 1980,53, 1263. V. F. Kalasinky and S. Pechsiri, J. , 1980,9, 120. A. B. Nease and C. J. Wurrey, J. , 1980,9, 107. M. Ceroni and U. , 1979, 3703. '12This method may prove useful for the determination of molecular weights of epoxides. -Ring-opening Reactions. e. (124; R = CD3), which indicates a mechanism proceeding via the dicyclopropylcarbinylintermediate (123; R = CH, or CD,). ' Gf) 0 , OH (125) o@ 0 HO (126) (127) The reactions of a number of steroidal A-ring epoxides with electrophiles have been reported.

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