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A review of the literature published between September 1976 by James Ralph Hanson; et al

By James Ralph Hanson; et al

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S. Hwang, 0. A. L. Hsieh, and D. B. S. , 1977, 25, 450. 174 A. A. Craveiro, F. J. A. Matos, and J. W. de Alencar, J. Chem. , 1976,53, 652. ''' ( a ) A. M. Humphrey, J. H. Greaves, B. E. Kent, W. S. Matthews, D. A. Moyler, R. G. Perry, J. Ridlington, R. A. Stocks, and G. Watson, Analyst, 1977,102,607; C. L. Goodwin and A. E. Squillace, Phytochemistry, 1976,15,1771; (b)C. H. Brieskorn and W. Schlicht, Pharm. , 1976,51,133. 176 J. Calderon, J. L. Munoz, L. Quijano, and T. Rios, Rev. Latinoamer. , 1976,7, 114 (Chem.

6, p. g. by the Matsui synthesis or the Sukh Dev modification (see Vol. 5 , p. 15, ref. 4 equivalents); the reaction probably proceeds via initial betaine formation at the aldehydic carbonyl group. 311A second paper reports the first one-pot stereospecific synthesis of (*)-cis-chrysanthemic esters by reaction of a-butenolide (108) 307 308 309 310 311 M. Bertrand, G. Gil, and J. Viala, Tefruhedron Letters, 1977, 1785. T. Aratani, Y. Yoneyoshi, and T. Nagase, Tefruhedron Letters, 1977, 2599; T. Aratani, Y.

258 0H /‘CH,OH 2,4,4,6-Tetrabromocyclohexa-2,5-dienone in methylene chloride promotes the biomimetic cyclization of linalool and dehydrolinalool to (60;R=vinyl or ethynyl) as the major product with minor amounts of (61; X = Br, R =vinyl or ethynyl) in contrast to brominative cyclization with N-bromosuccinimide when (61 ; X = Br, 25’ 252 253 254 255 256 257 258 S . 4 . Hashimoto, S . 4 . Yamada, and K. Koga, J. Amer. Chem. ,1976,98,7450. Klein and W. , 1977,24,55. J. Chan and H. M. S. P. 4 006 196 (Chem.

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